<p dir="ltr">A retrofill solution of non-switching high-voltage SF<sub>6</sub> equipment using an environmentally friendlier alternative is an emerging solution different to a new-build approach where existing SF<sub>6</sub> equipment is decommissioned and replaced with new equipment. This work develops a streamer criterion model to enable the screening of a large number of SF<sub>6</sub> alternatives under representative parameters for retrofill application. Different operational parameters relevant to practical applications have been experimentally investigated under 50 Hz AC voltage waveform for absolute pressures of 1-6 bar, quasi uniform geometries with field utilization factors of 0.55-0.69 and average maximum surface roughness of 8–46.6 µm. The combined experimental and modeling validations inform that a 20% C<sub>3</sub>F<sub>7</sub>CN and 80% CO<sub>2</sub> mixture has a comparable dielectric performance as SF<sub>6</sub> over a wide-ranging conditions representative of gas-insulated line/busbar (GIL/GIB). Thus, this work demonstrates that a C<sub>3</sub>F<sub>7</sub>CN/CO<sub>2</sub> mixture is suitable for retrofilling the existing SF<sub>6</sub>-designed equipment, which provides an economical and time saving approach that will expedite the transition to a more sustainable electricity grid through the complete phase-out of SF<sub>6</sub>.</p>