<p dir="ltr">Condition monitoring of gas insulated high voltage equipment is important to ensure reliable operation of electricity networks. Partial discharge (PD) monitoring is well established for existing SF<sub>6</sub> equipment, but still in its infancy for the emerging SF<sub>6</sub> alternatives as the power industry transitions from SF<sub>6</sub>. PD characteristics of 20% C<sub>3</sub>F<sub>7</sub>CN / 80% CO<sub>2</sub> gas mixture as a viable retrofill solution were extensively investigated over extended energization periods in a busbar demonstrator designed for SF<sub>6</sub> and rated to 420/550 kV. Protrusions of 3, 5, 10 and 15 mm needle lengths were used on the high voltage conductor for comparative PD investigations of SF<sub>6</sub> and 20% C<sub>3</sub>F<sub>7</sub>CN / 80% CO<sub>2</sub> gas mixture. PD activity was measured with IEC 60270 (apparent charge) and ultra-high frequency (UHF) detection methods. The PD patterns recorded for all needle lengths were representative of a protrusion-on-conductor defect and the two PD detection methods were comparable. For identical defect lengths, SF<sub>6</sub> showed a comparatively longer time-to-breakdown when compared to a 20% C<sub>3</sub>F<sub>7</sub>CN / 80% CO<sub>2</sub> mixture. Results obtained in a controlled laboratory environment demonstrate wider applicability to field measurements of C<sub>3</sub>F<sub>7</sub>CN based mixtures adopted for retrofill application in SF<sub>6</sub>-designed gas insulated busbar.</p>