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Research data supporting the publication "Enhanced spin lifetime in colloidal quantum dots by growth from singly Mn-doped molecular cluster seeds"

Version 2 2025-04-07, 10:04
Version 1 2025-03-18, 16:34
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posted on 2025-04-07, 10:04 authored by Christopher Page, Julian Schneider, James Harris, Nigel L. Pickett, Nathalie C. Gresty, Christopher Waby, Charles Biddlecombe, Rachel M Barrett, Adam BrookfieldAdam Brookfield, Patrick ParkinsonPatrick Parkinson, Floriana Tuna, Simon M. Fairclough, David BinksDavid Binks
<p dir="ltr">Doped colloidal quantum dots (CQDs) are promising spin-photon interfaces, combining excellent optical properties and a substrate-free, nano-positionable platform. Here, we report the synthesis of InP/ZnSeS core-shell CQDs from zinc sulphide based seed clusters containing single Mn(II) ions. The resulting doped CQDs demonstrate photoluminescence quantum yields up to 70%, a spin-lattice lifetime of 22 ms and a spin coherence lifetime of 2.7 μs, greater than and similar to the best yet reported for Mn-doped CQD systems, respectively. These spin lifetimes were achieved despite the high nuclear spin of InP, demonstrating the effectiveness of the ZnS cluster in shielding the Mn from its environment.</p>

Funding

Singly-doped Colloidal Quantum Dots for Quantum Technology

UK Research and Innovation

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Big-data for nano-electronics

UK Research and Innovation

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Sir Henry Royce Institute - Cambridge Equipment

Engineering and Physical Sciences Research Council

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Sir Henry Royce InsStitute - recurrent grant

Engineering and Physical Sciences Research Council

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A National Research Facility for EPR Spectroscopy, 2022-2027

Engineering and Physical Sciences Research Council

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EPR NRF Core Equipment Bid

Engineering and Physical Sciences Research Council

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EP/X034523/1

Multi-Dimensional Electron Microscope

Engineering and Physical Sciences Research Council

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